|
|
|
|
|
|
|
|
|
|
|
|
|
Chapter 1
.
Introductory thermodynamics
.
|
1
|
|
1.1
. Equilibrium
1.2
. Internal
energy
1.3
. Heat content
or enthalpy
1.4
. Entropy
1.5
. Free energy
|
1
2
2
3
10
|
|
|
|
|
Chapter 2
.
Thermodynamics of solutions
.
|
14
|
|
2.1
. Solutions
2.2
. Heterogenous
equilibrium-the phase rule
2.3
. Free energy
of solutions
2.4
. The free
energy of phase mixtures
2.5
. Variation of
solubility with temperature
|
14
21
30
36
40
|
|
|
|
|
Chapter 3
.
Binary phase diagrams
Two-phase equilibrium
|
42
|
|
3.1
. Introduction
3.2
. Two phase
equilibrium. Complete solubility of the
components in both the
liquid and the solid state
.
|
42
43
|
|
|
|
|
Chapter
4
.
Binary phase diagrams
Three-phase equilibrium involving limited solubility of the components in the solid state
but complete solubility in the liquid state
|
64
|
|
4.1
. Structural
factors
4.2
. Three-phase
equilibrium-eutectic reactions
4.3
. Three-phase
equilibrium-peritectic reactions
4.4
. Congruent
transformations
|
64
65
80
91
|
|
|
|
|
Chapter 5
.
Binary phase diagrams
Limited solubility in both the
liquid and solid state
|
94
|
|
5.1
. Introductory
thermodynamics
5.2
. Monotectic
reactions
5.3
. Syntectic
reactions
|
94
96
100
|
|
|
|
|
Chapter 6
.
Binary phase diagrams
Reactions in the solid state
|
102
|
|
6.1
. Solid state
reactions
6.2
. Eutectoïd reactions
6.3
. Monotectoïd
reactions
6.4
. Peritectoïd
reactions
|
102
103
109
110
|
|
|
|
|
Chapter 7
.
Binary phase diagrams
Allotropy of the components
|
113
|
|
7.1
. Systems in
which one phase is in equilibrium with the liquid
phase
7.2
. Systems in
which two phases are in equilibrium with the liquid phase
|
113
115
|
|
|
|
|
Chapter 8
.
Ternary phase diagrams
Two-phase equilibrium
|
118
|
|
8.1
. Introduction
8.2
.
Representation of ternary systems
8.3
. Tie lines
and tie triangles
8.4
. Two-phase
equilibrium. Complete solubility of the
components in both the liquid and the solid
state
|
118
119
122
125
|
|
|
|
|
Chapter 9
.
Ternary phase diagrams
Three-phase equilibrium
|
143
|
|
9.1
. Properties
of three-phase tie triangles
9.2
.
Three-phase equilibrium produced by the coalescence of
miscibility gaps
9.3
. Three-phase
equilibrium involving eutectic reactions
9.4
. Three-phase
equilibrium involving peritectic reactions
|
143
145
149
168
|
|
|
|
|
Chapter 10.
Ternary phase diagrams
Four-phase equilibrium
|
173
|
|
10.1
. The
eutectic equilibrium
l = α+β+γ
10.2
. Variants of
the ternary eutectic diagram
10.3
. The
quasi-peritectic equilibrium
l+α = β+γ
10.4
. T
he ternary peritectic
equilibrium
l+α
+
β = γ
|
173
181
184
194
|
|
|
|
|
Chapter 11
.
Ternary phase diagrams
Intermediate phases
.
|
199
|
|
11.1
.
Congruently-melting intermediate phases
11.2
.
Incongruently-melting intermediate phases
|
199
210
|
|
|
|
|
Chapter 12
.
Ternary phase diagrams
Liquid immiscibilty
|
218
|
|
12.1
. Two binary
systems are monotectic
12.2
. One binary
system is monotectic
12.3
. None of the
binaries contain liquid miscibility gaps but
true ternary liquid immiscibility appears
.
|
218
220
223
|
|
|
|
|
Chapter 13
.
Ternary phase diagrams
Four-phase
equilibrium involving allotropy of one component
|
224
|
|
|
|
|
Chapter 14
.
The association of phase regions
.
|
230
|
|
14.1
. Law of
adjoining phase regions
14.2
. Degenerate
phase regions
14.3
.
Two-dimensional sections of phase diagrams
14.4
. The cross
rule
14.5
. Non-regular
two-dimensional sections
14.6
. Critical
points
14.7
. Association
of phase regions in multi-components systems
|
230
232
235
239
239
248
248
|
|
|
|
|
Chapter 15
.
Quaternary phase diagrams
.
|
249
|
|
15.1
.
Representation of quaternary systems
15.2
.Two-phase
equilibrium
15.3
. Three-phase
equilibrium
15.4
. Four-phase
equilibrium
15.5
. Five-phase
equilibrium
15.6
.
Two-dimensional polythermal sections
15.7
. Complex
quaternary systems
|
249
253
256
264
272
280
280
|
|
|
|
|
Appendix
.
Selected bibliography
.
|
|
|
Index
.
|
|