A
- A1, A3, Acm lines -
106
- A1, A2, A3, A4 change points -
103
- acicular eutectic structure -
69
- activity -
18
- equality in co-existing phases -
24
- of pure component -
18
- relation to free energy -
18
- activity coefficient -
20
- of an ideal solution -
20
- of actual solution -
20
- activity-composition curves,
20,
40,
95
- actual solutions -
20-21,
47
- free energy of formation -
21
- adjoining phase regions, law of -
230-232,
269
- Ag-Al -
111
- Ag-Au-Pt -
171
- Ag-Cu -
41,
43,
74,
172
- Ag-Cu-Ni -
172
- Ag-Li -
43
- Ag-Ni -
172
- Ag-Pt -
81,
171
- Ag-Tl -
95
- Al-Cu -
43,
90,
103,
108,
110
- Al-Cu-Si -
180
- Al-Mg-Si -
201
- Al-Mg-Zn -
198,
217
- Al-Sb-Zn -
201
- Al-Si -
74,
93
- Al-Sn -
74
- Al-Zn -
109
- allotropic transformation -
103,
113
- allotropy -
103,
113
- alphabet, greek,
67
- A NDERSON, J.S. -
90
- A RMANTROUT, CE.,
114
- arsenic,
- triple point,
30
- sublimation,
30
- As-Ga,
204
- As-Ga-Zn,
204
- As-Zn,
204
- association of phase regions,
143,
230-248
- atomic fraction,
6,
15
- atomic factor,
64
- Au-Co-Pd,
166
- Au-Cu-Ni,
142
- Au-Cu-Pd,
148
- Au-Ge-Sb,
191
- Au-Ni,
56,
57
- Au-Pd-Pt,
141
- Au-Pt,
41,
80,
171
- Au-Sn,
20
- Au-Tl,
95
- austenite,
105,
107
- Avogadro's number,
5,
7
- A XON, H.J.,
96
B
- BARRETT, C.S.,
72
- B ELAÏEW, N.T.,
72
- B ENESOVSKY, F.,
198
- B ERAK, I.,
223
- B ERGMANN, A.,
172
- bertholide phase,
87
- Bi-Cd-Pb,
274
- Bi-Cd-Pb-Sn,
274-279
- Bi-Cd-Sn,
274
- Bi-Cu-Mg,
208,
209-210,
214
- Bi-Pb-Sn,
274
- Bi-Sn,
20
- binary "eutectic-type" reaction,
167
- binary system,
27,
42-117
- bismuth, melting curve,
30
- bivariant equilibrium,
- binary systems,
42
- quaternary systems,
256-264
- ternary systems,
118,
125-142
- unary systems,
28
- Boltzmann's constant,
5
- Boltzmann's relation,
5,
6
- boundary intersections,
- binary systems,
78-79
- ternary isothermal sections,
144
- B RAUN, H.,
85
- B ROPHY, J.H.,
194
- B ROWN A.,
84 (Fig. ref.)
- B UDENNAYA, L.D.,
166
C
- C -Cr-Fe,
225
- C-Fe - 43,
103-108,
117,
221,
224
- C-Fe-Mo,
225
- C-Fe-S,
221
- C-Fe-Si,
225
- C-Fe-W,
225
- C-Ti,
198
- C-Ti-W,
198
- Ca-Cd,
100
- C AMPBELL, A.N.,
119
- C AYRON, R.,
265,
280
- Cd-Ga-Pb,
218-220
- Cd-Pb,
20
- Cd-Pb-Sn,
274
- Cd-Zn,
74,
75 (footnote)
- cementite,
105
- decomposition of,
107
- C HADWICK, G.A.,
69
- C HALMERS, B.,
54
- change point,
103
- C HANNEL- E VANS, K.M.,
64
- C HASTON, J.C.,
41
- chemical equilibrium,
1
- chemical potentiel,
22
- equality in co-existing phases,
22-24
- C HERVOYAKOVA, V.V.,
110
- C HRISTIAN, J.W.,
130,
184
- C LARK, J.B.,
198,
217
- Clausius-Clapeyron equation,
28
- C LEWS, C.J.B.,
92
- closed or isolated system,
2,
9-10
- entropy of,
10
- Co-Fe-Mn-U,
135
- Co-Os,
115
- Co-Re,
115
- Co-Ru,
115
- coalescense of miscibility gaps (ternary systems),
-
145-148
- complete immiscibility,
74
- complexion,
4
- component, definition,
25
- composition,
- quaternary representation,
249-252
- ternary representation,
118,
119-122
- compounds, intermetallic,
85
- concentration triangle (ternary systems),
126,
152
- condensed phase,
27
- congruent intermediate phase,
- binary systems,
91-93
- ternary systems,
199-200
- congruent melting,
- binary systems,
58,
91-93
- ternary systems,
164,
199-200
- conjugate phases,
128,
130,
131,
140,
142,
143,
256
- conode,
50
- constitutional undercooling,
54
- continuous series of solutions,
- binary systems,
43-63,
113
- quaternary systems,
253-256
- ternary systems,
125-138
- cooling curves,
70,
73
- co-ordination number,
31
- C OPELAND, M.I.,
114
- cored structure,
54-55,
74,
135,
256
- C OTTREL, A.H.,
80,
89 (Fig. ref.)
- Cr-Fe,
114
- criteria for ternary monovariant reactions,
153-155
- critical curve,
139
- critical phase,
57
- critical point,
- binary systems,
56-57
- ternary systems,
138,
142,
149-166,
169-170,
220
- unary systems,
59
- critical temperature,
40,
56,
65,
91,
97,
158,
220
- hypothetical,
65
- cross rule,
239,
241
- Cs-K,
56
- Cu-Fe-P,
223
- Cu-Ga,
86
- Cu-Ge,
75,
76
- Cu-Mg-Sb,
210
- Cu-Ni,
172
- Cu-Pb,
43,
98,
99
- Cu-Si,
76
- Cu-Sn,
86,
11
- Cu-Tl,
95
- Cu-W,
99
- Cu-Zn,
25,
43,
58,
65,
88,
89
D
- daltonide phase,
87
- D ARKEN, L.S.,
74,
90
- D ARLING, A.S.,
41
- D AVIES, G.J.,
112
- degenerate phase region,
232-235
- degenerate tie line,
62,
97,
140,
142,
145
- degenerate tie triangle,
145,
148,
152,
158,
166,
169,
170,
214,
220,
260
- degree of freedom,
26
- depression of freezing point,
51
- derivation of partial molar-from molar quantities,
15
- derivation of phase rule,
25-26
- diffusioess transformation,
59
- dimension of phase boundaries,
230-248,
269
- disordered phase,
58
- disposition of phase boundaries (binary systems),
78-79
- distribution coefficient,
52,
139
- divorced eutectic,
98,
99,
101
- D OBBENER, R.,
208,
210
- D ULLENKOPF, W.,
217
- D UNKERLEY, F.J.,
96
E
- electron compound,
86
- electronegative valency effect,
64
- emulsion of immiscible liquids,
99
- energy of an interface,
51
- E NGEL, A.,
142
- enthalpy,
1,
2-3
- change in forming ideal solution,
19
- change in forming non-ideal solution,
31
- of homogeneous solutions,
30
- of an ideal solution,
31
- of mixing,
95
- entropy,
1,
3-10
- as a measure of disorder,
5
- at absolute zero,
8
- atomistic concept of,
4-7
- dimension of,
5
- of fusion,
77
- of impossible reactions,
10
- of isolated systems,
10
- of mixing,
5-7,
19,
32,
74
- of reactions in equilibrium,
10
- of spontaneous reactions - 10
- thermodynamic definition - 7-10
- equality of activity in co-existing phases,
24
- equality of chemical potential in co-existing phases - 22-24
- equality of composition in two-phase equilibrium - 44
- equilateral tetrahedron, representation of quaternary
- composition by,
249
- equilateral triangle, representation of ternary
- composition by,
120
- equilibrium,
1
- bivariant,
28,
42,
118,
125-142,
256-264
- chemical,
1
- diagram ( see phase diagram)
- heterogeneous,
21-30
- homogeneous,
21
- invariant,
27,
43,
65-93,
96-112,
114-117,
119,
173-229,
-
272-279
- mechanical,
1
- metastable,
1
- monovariant,
28,
42,
43-63,
119,
143-172,
264-272
- stable,
1
- thermal,
1
- thermodynamic,
1
- trivariant,
118,
125,
253-256
- unstable,
1
- eutectic diagram, limiting form of,
74-75
- eutectic point,
67,
174,
278
- eutectic reaction,
- binary systems,
43,
65-79,
105
- quaternary systems,
272-273,
274-279
- ternary systems,
124,
149-168,
173-184
- eutectic solidification,
68-70,
179-180,
278-279
- eutectic structure,
69,
98,
179
- eutectoid reaction (binary systems),
43,
103-108
- excess free energy,
21
- extensive quantity,
4
- extensive thermodynamic functions,
14
F
- FAST J.D.,
58
- favourable size-factor,
64
- Fe-Ni,
117
- Fe-O,
90
- Fe-P-Sb,
223
- Fe-S,
221
- Fe-Sb-Si,
223
- Fe-U,
92
- Fe-V,
114
- Fe-Zr,
117
- ferrite,
105
- F INDLAY, A.,
119
- first law of thermodynamics,
2,
7
- five-phase equilibrium (quaternary systems),
272-279
- four-phase equilibrium,
- quaternary systems,
264-272
- ternary systems,
119,
124-125,
173-198,
199-217,
-
218-223,
224-229
- four-phase plane (ternary systems),
124-125,
152,
173,
-
184,
198
- four-phase plane as function of four tie triangles,
124,
-
175,
184,
198
- freedom, degree of,
26
- free energy,
1,
10-13
- at constant pressure,
11
- at constant volume,
11
- change in a reversible reaction,
11
- change in an irreversible reaction,
11
- composition curve,
32-36,
38,
44,
55,
56,
66,
80,
-
88,
90,
95,
98,
116
- of binary phase mixtures,
36-40
- of solutions,
19,
21,
30-36
- surfaces,
135
- variation with temperature,
12
- free enthalpy,
11
- freezing of binary alloys,
- eutectic,
68-70
- hyper-eutectic,
73-74
- hypo-eutectic,
70-73
- isomorphous series,
51-54
-
98-99
- non-equilibrium,
54-55,
74,
84-85
- peritectic,
81-83
- syntectic,
100
- with retrograde solubility,
78
- freezing of quaternary alloys,
256,
261-264,
271-272,
-
278-279
- freezing of ternary alloys,
- isomorphous series,
132-135
- monovariant eutectic system,
162-165
- non-equilibrium,
135
- ternary eutectic system,
179-180
- ternary quasi-peritectic system,
184-186,
191
- F ULLER, C.S.,
76
G
- Ga-In-Sn,
180
- Ga-Pb,
98
- Ga-Tl,
98
- Ga-Zn,
204
- gallium, melting curve,
30
- gas constant,
5
- Gd-Zr,
114
-
76
- Ge-Si -
45
- Gibbs free energy -
1,
10-13,
21
- G IBBS, J.W. -
25,
27,
57,
59,
120,
148
- Gibbs phase rule,
25-26
- Gibbs triangle,
120
- globular eutectic structure,
69
- G OLDAK, G.R.,
110
- G ORBAN, Y U.A.,
110
- grain size,
52,
103
- gram atom,
14
- graphitisation,
107
- greek alphabet,
67
- grey tin,
3,
10
- G RIGORIEV, A.T.,
166
- G ROGAN, J.D.,
92
- G UERTLER, W.,
105,
172
- G URRY, R.W.,
74,
90
- G UTHRIE, F.,
105
H
- HANNEMANN, H.,
26 1
- H ARDY, H.K.,
41,
203
- H AUG, K.,
202,
203
- heat capacity,
2
- heat content,
1,
2-3
- in standard state,
3
- Helmohltz free energy,
1,
11
- Henry's law,
20
- heterogeneous equilibrium,
21-30
- heterogeneous nucleation,
51
- H EYMER G.,
56
- Hf-W,
85,
90
- Hg-K-Na,
208
- H ILDEBRAND, J.H.,
96
- H ILLERT, M.,
153,
171
- Hillert criterion,
154-155,
166,
170,
265
- H ODGKINSON, R.J.,
76,
90
- H OLLOMON, J.H.,
51
- homogeneous equilibrium,
21
- homogeneous nucleation,
51
- homogenisation of cored solutions,
54-55
- H ORN, E.,
115
- H ORSTMANN, D.,
223
- H OWE, H.M.,
05
- H UME- R OTHERY, W.,
3,
55,
64,
86,
109,
110,
-
111 (Fig. ref),
130,
184,
203
- hyperbolic point,
136
- hyper-eutectic alloys,
70,
73-74
- hyper-eutectoid alloys,
107
- hypo-eutectic alloys,
70-73
- hypo-eutectoid alloys,
107
- hypothetical critical temperature,
65
I
- ice, melting of,
9
- ideal solution,
17-20
- entropy of mixing,
5-7,
19
- free energy of mixing,
19
- Raoult's law for,
18
- idiomorphic crystallisation,
93
- immiscibility, liquid,
94-101,
138,
218-223
- impossible phase diagrams,
74,
79,
144-145
- incipient immiscibility,
94-95
- incongruent intermediate phase,
- binary systems,
85-90
- ternary systems,
210-217
- incongruent melting,
87-90,
210-217
- intensive quantity,
4
- interaction energy in solutions,
30
- interfacial energy,
51,
102-103
- intermediate phase,
- binary,
64,
85-91,
100
- classification,
86-87
- electron compound,
86
- interstitial compound,
86
- normal valency compound,
86
- size-factor compound,
86
- ternary,
208-210,
213-217
- intermetallic compound,
85
- internal energy,
1,
2
- intersection of phase boundaries,
- binary systems,
78-79
- ternary isothermal sections,
144
- intersection of tie lines,
128,
145-147
- interstitial compounds,
86
- invariant equilibrium,
- binary systems,
43,
65-93,
96-112,
114-117
- quaternary systems,
272-279
- ternary systems,
119,
124-125,
173-229
- unary systems,
27
- ionic compounds,
86
- Ir-Pd,
41
- Ir-Pt,
41
- iron,
- allotropy of,
103
- Curie point,
103
- irreversible process,
8,
9,
10,
11
- free energy change in,
12
- isobaric-isothermal sections,
252,
254-256,
258-261,
-
267-270
- isolated system,
2,
9-10
- entropy of,
10
- isomorphous alloy systems,
- binary systems,
43-63,
113
- quaternary systems,
253-256
- ternary systems,
125-138
- isopleth,
130
- isothermal section,
127-130,
138,
139,
142,
147,
156-159,
-
166,
169,
177,
187,
198
- boundary intersection of,
144
- IVANOV O.S.,
153
- I YUTINA, I.A.,
166
J
- J ACKSON, R.J.,
109
- JÄNECKE, E.,
208,
210
- J ENKINS, C.H.M.,
75
- J EWETT, R.P.,
110
- J OFFE, J.,
239
K
- K-Pb,
100
- K-Zn,
43,
100
- K AMDAR, M.H.,
194
- K ATO, H.,
114
- K IEFFER, R.,
198
- K IESSLER, G.,
135
- konode,
50
- Konovalov's rule,
128-130,
256
- KÖSTER, W.,
115,
202,
203,
204,
206,
217
- KREMERS, K.,
89
- KRESTOVNIKOV, A.N.,
62
- KUBASCHEWSKI, O.,
47,
48,
49,
56,
92
- KUPFER, A. Y A.,
73
- KURNAKOV, N.S.,
87,
204
- Kurnakov's rule,
204
L
- LAAR, J.J. VAN,
75
- lamellar eutectic structure,
69
- L ANDAU, A.I.,
230,
239,
24 1,
248,
270,
275,
280
- L ARSEN, W.L.,
109
- lattice, co-ordination number of,
31
- laves phase,
86,
92
- law of adjoining phase regions,
230-232,
269
- modification at critical points,
248
- law of thermodynamics,
- first,
2,
7
- second,
10
- lever rule,
- binary systems,
36-37,
53,
68,
71,
114,
122
- quaternary systems,
256
- ternary systems,
122-125,
128,
133,
186
- limiting forms of phase diagrams,
74,
89,
92,
99,
111,
167
- Lipowitz's alloy,
274
- L IPSON, H.,
90,
145
- liquid immiscibility,
- binary systems,
94-101
- ternary systems,
138,
218-223
- liquid to solid transformation mechanism,
51-52
- liquidus,
50
- L LEWELYN L EACH, J.S.,
110
- L UMSDEN, J.,
18,
95
M
- M ABBOTT, G.W.,
64
- M ACK D.J.,
110
- M AKSIMOVA, M.V.,
166
- M ASING G.,
230
- mechanical equilibrium,
1
- M EIJERING, J.L.,
76
- melting curve,
30
- for Bi and Ga,
30
- melting of ice,
9
- metastable equilibrium,
1
- metatectic composition,
115
- metatectic reaction,
43,
110,
115-117
- Mg-Pb,
64,
86,
92
- Mg-Sb,
86
- Mg-Si,
64
86,
92 li>
- Mg-Sn,
64,
86,
92
- M ILLS, G.J.,
96
- M INTERN, R.A.,
41
- miscibility gap,
- binary systems,
40-41,
56-57,
94-101
- coalescence in ternary systems,
145-148
- ternary systems,
138-142,
145-148,
218-223
- molar quantities,
- partial,
14-16
- relative,
16-17
- molar volume,
14
- mole,
14
- mole fraction,
15
- monotectic reaction,
43,
96-99
- limiting form of,
99
- monotectic temperature,
96
- monotectoid reaction,
109-110
- monovariant equilibrium,
- binary systems,
42,
43-63
- quaternary systems,
264-272
- ternary systems,
119,
143-172
- unary systems,
28,
59
- monovariant eutectic, ternary systems,
149-168
- monovariant peritectic, ternary systems,
168-171
- Mo_Ti,
113
- M OTT, B.W.,
96
N
- Na-Zn,
100
- N EWKIRK, J.B.,
59
- nodal plexus,
- definition of,
239
- formation of,
241
- opening of,
241
- types of,
241
- non equilibrium freezing,
- binary systems,
54-55,
74,
84-85
- ternary systems,
135
- non-regular sections,
239-248
- distribution of phases in,
241
- non-stoichiometric compounds,
90-91
- normal valency compounds,
86,
92
- N ORREYS, J.J.,
84 (Fig. ref.)
- N OVIKOVA, O.A.,
171
- N OWOTNY, H.,
198
- nucleation,
- heterogeneous,
51
- homogeneous,
51
O
- order-disorder transformation,
58-59,
112
- ordered structure,
58
- O SMOND F.,
105
P
- PALATNIK, L.S.,
230,
239,
241,
248,
280
- P ARR, J.G.,
110
- P ARRAVANO, N.,
274
- P ARTHE, E.,
198
- partial molar free energy,
22
- partial molar quantities,
14-16
- derivation from molar quantities,
15
- partial molar volume,
14
- partial phase diagram,
- binary systems,
92,
105
- ternary systems,
198,
199,
221
- partial re-melting,
78,
115
- Pb-Sb,
74
- Pb-Sn,
73,
74
- Pb-Sn-Zn,
120
- Pb-U,
100
- Pb-Zn,
96
- pearlite,
105
- P EARSON, W.B.,
130,
184
- P ELZEL, E.,
99
- peritectic diagram, limiting form of,
88-89
- peritectic reaction,
- binary systems,
43,
80,
105,
115
- quaternary systems,
272,
274
- ternary systems,
124,
173,
194-198
- peritectic reaction rim,
84-85
- peritectic temperature,
81
- peritectoid reaction,
43,
110-112
- P ETZOW, G.,
135
- phase,
- definition of,
25
- condensed,
27
- phase boundaries,
- intersection in binary systems of,
78-79
- intersection in ternary isothermal sections of,
144
- phase diagram,
- definition of,
42
- of pure metal,
27-30
- partial,
92,
105,
198,
199,
221
- phase mixture, free energy of binary,
36-40
- phase regions, association of,
143,
230-248
- phase rule,
25-30,
65,
118-119
- and intersection of tie lines,
128
- and order-disorder transformations,
58-59,
112
- and restriction on disposition of phase regions,
230
- application to binary critical points,
57
- application to binary minima,
56
- application to coalescence of miscibility gaps,
145
- application to ternary critical points,
139
- derivation of,
25-26
- for condensed phases,
27,
118
- phase separation,
56
- P HILLIPS, H.W.L.,
111,
203,
280
- plait point,
139
- plait point curve,
139
- P LATE, W.,
41
- plutonium, allotropy of,
113
- polythermal projection,
126,
252
- potential, chemical,
22
- P REDEL, B.,
98,
218,
220
- P RESNYAKOV, A.A.,
110
- pressure-composition (P-x) diagram,
59
- pressure-temperature-composition (P-T-x) diagram,
-
59-63
- primary crystallisation,
72,
93,
176
- P RINCE, A.
73,
203
248,
270
- pro-eutectoid,
107
- pseudo-binary section,
132,
198,
199,
204,
208,
214,
-
217,
221
Q
- quasi-binary section,
132,
198,
199,
204,
208,
214, 217, 221
- quasi-peritectic reaction -
125,
173,
184-194
- quasi-ternary section,
135
- quaternary eutectic point,
278
- quaternary eutectic reaction,
272-273,
274-279
- quaternary peritectic reaction,
272,
274
- quaternary 2-3 quasi-peritectic reaction,
272-273
- quaternary 3-2 quasi-peritectic reaction,
272,
274
- quaternary system,
27
- isobaric isothermal sections,
252,
254-256,
258-261,
-
267-270
- representaion of composition of,
249-252
- three-dimensional polythermal sections,
252
- tie hexahedra in,
273
- tie lines in,
253
- tie tetrahedra in,
264-265
- tie triangles in,
256
- two-dimensional polythermal sections,
252-253,
-
261-262,
270,
280
- quinary system,
27
R
- RAND, M.H.,
47,
48,
49
- Raoult's law,
18
- deviations from,
20
- R AUB E.,
> 41,
142,
148
- R AYNOR, G.V.,
43,
64,
86,
88 (Fig. ref.),
89,
110,
-
111 (Fig. ref.),
203
- Re-Ta,
194
- Re-Ta-W,
194
- Re-W,
194
- reaction rim, peritectic,
84-85
- regular solution,
47
- rejection of solute,
52
- relative molar quantities,
16-17
- relative valency effect,
65
- representation of composition,
- quaternary systems,
249-252
- ternary systems,
118,
119-122
- retrograde solidus curve,
75-78
- retrograde solubility,
75-78
- reversible process,
8,
10,
11
- free energy change in,
11
- R HINES, F.N.,
59,
133,
207
- Rhines' rule,
207
- right-triangular prism,
121
- R OBERTS -A USTEN, W.C.,
105,
274
- R OBINS, D.A.,
90
- R OGERS, B.A.,
230
- R OOZEBOOM, H.W.B.,
144,
148
- R OSE, W.,
208
- R OSENTHAL, F.D.,
96
- rotation of tie lines,
128-130,
133,
141
- R UDBERG, F.,
73
- RUDNITSKIY, A.A.,
171
- R UDY, E.,
85
- R UER, R.,
89
- ruled surfaces,
143,
256
- R USHBROOKE, G.S.,
90
- R UTTER, J.W.,
54
S
- saddle point,
136,
152,
201,
203
- S CHEIL, E.,
69,
210
- S CHRADER, A.,
261
- S CHRAMM, J.,
89
- S CHREINEMAKERS, F.A.H.,
144,
145,
148
- S COTT, R.L.,
96
- second law of thermodynamics,
10
- senary system,
27
- S IBERT, W.,
210
- sigma phase,
114
- S IROVICH, G.,
274
- size-factor compound,
86
- skew surface,
133,
140,
143,
165,
171
- S MITH, C.S.,
87,
208
- S MITH, N.O.,
119
- Sn-Ti-V,
203
- S OKOLOVSKAYA, E.M.,
166
- solid solution,
5
- entropy increase on formation of,
5-7
- solid state transformation,
102-112
- solidus,
50
- retrograde,
75-78
- solubility,
33,
39,
67
- curve,
40-41,
67
- factors influencing,
64-65
- of Cu in Ge,
75
- of Cu in Zn,
65
- of metastable phases,
79,
107
- of Pb in Mg,
64
- of Si in Mg,
64
- of Sn in Mg,
64
- of Zn in Cu,
65,
89
- retrograde,
75-78
- variation with temperature,
40-41,
67 >
- solute rejection,
52
- solutions,
14-21
- actual,
20-21
- energy of,
30
- enthalpy of,
30
- free energy of,
19,
21,
30-36
- ideal,
17-20
- interaction energy in,
30
- ordering of,
58
- partial molar quantities,
14-16
- relative molar quantities,
16-17
- statistical model of,
30
- solvus curve,
67
- space diagram,
125
- S PENGLER, H.,
180
- standard state,
3
- state of a system,
2
- state space,
125,
143,
230
- S TEEB, S.,
135
- steel,
107,
224
- Stirling's theorem,
6
- S TOCKDALE, D.,
90
- stoichiometric composition,
90
- S TOKES, G.G.,
120,
142
- strain energy factor,
103
- S TRUTHERS, J.D.,
75,
76,
77,
78
- sublimation curve,
29
- of arsenic,
30
- superlattice,
58-59,
91
- S WALIN, R.A.,
45
- syntectic reaction,
43,
100-101
- syntectic temperature,
100
T
- Ta-Ti
113
- Ta-Zr,
109
- tabular representation of ternary equilibria,
187-189,
191,
-
207,
212,
217,
219,
222,
223,
226
- terminal solid solution,
67
- termination of ternary tie triangles,
152-153
- ternary,
- alloys, representation of composition,
118,
119-122
- critical point,
142
- equilibria, tabular representation of,
187-189,
191,
-
207,
212,
217,
219,
222,
223,
226
- eutectic point,
174
- eutectic structure,
179
- eutectic system,
124,
173-180
- four-phase monotectic reaction,
218-223
- intermediate phase,
208-210,
213-217
- peritectic reaction,
124-125,
173,
194-198
- quasi-peritectic reaction,
125,
173,
184-194
- saddle point,
136,
152,
210,
203
- space diagram,
125
- space diagram, junction of phase regions,
235
- system,
27,
118
- tetrahedron, representation of quaternary systems by,
-
249-252
- thermal analysis,
73
- thermal equilibrium,
1
- thermodynamic,
- equilibrium,
1
- potential,
11
- relations,
13
- thermodynamics,
- chemical potential,
22-24
- enthalpy,
1,
2-3
- entropy,
1,
3-10
- first law of,
2,
7
- free energy,
1,
10-13
- free energy curves,
32-36,
38,
44,
55,
56,
66,
80,
88,
-
90,
95,
98,
116
- free energy of phase mixtures,
36-40
- free energy of solutions,
19,
21,
30-36
- Gibbs free energy,
1,
10-13
- Helmholtz free energy,
1,
11
- internal energy,
1,
2
- of actual solutions,
21
- of binary liquid immiscibility,
94-96
- of binary two-phase equilibria,
43-51
- of ideal solutions,
19
- of solutions,
14-41
- partial molar free energy,
22
- partial molar quantities,
14-16
- relative molar quantities,
16-17
- second law of,
10
- T HOMAS, D. L LYOD,
110
- T HON, C.,
120
- three phase equilibrium,
- binary systems,
65-117
- quaternary systems,
256-264
- ternary systems,
143-172
- unary systems,
27
- T HURMOND, C.D.,
45,
75,
76,
77,
78
- Ti-W,
198
- Ti-Zr,
114
- T IEDEMA, T.J.,
41
- tie hexahedra,
273
- tie lines,
- binary systems,
50
- quaternary systems,
253-254
- ternary systems,
122-125
- tie tetrahedra,
265
- tie triangles,
- quaternary systems,
256
- ternary systems,
122-125
- T ILLER, W.A.,
69
- tin,
- allotropy of,
3,
8
- grey,
3,
10
- transformation of,
3,
8
- white,
3,
10
- titanium, allotropy of,
113
- T OORN, L.J. VAN DER,
41
- triangulation of ternary systems,
203,
211
- triple point,
28
- of arsenic,
30
- trivariant equilibrium,
- quaternary systems,
253-256
- ternary systems,
118,
125
- T URNBULL, D.,
51
- two-dimensional diagram,
- boundary between phase regions in,
235-238
- number of lines at a point in,
236-238
- two-phase equilibrium,
- binary systems,
43-63
- quaternary systems,
253-256
- ternary systems,
125-142
- unary systems,
36
U
- U-Zr -
48
- free energy curves,
48-50
- U LRICH, W.,
204,
206
- unary systems,
27-30,
59
- sublimation curve,
29
- triple point,
28
- vapourisation curve,
29
- undercooling,
51
- constitutional,
54
- of Ni,
51
V
- van't Hoff relation,
51,
218
- vapourisation curve,
29
- variance,
26
- vertical sections,
126,
130-132
- V IGDOROVICH, V.N.,
62
- V OGEL, R.,
144,
210,
221,
223
W
- WEST, D.R.F.,
110
- white tin,
3,
10
- WIDMANSTÄTTEN, A. DE,
72
- Widmanstätten structure,
72
- W ILLIAMS, D.E.,
109
- W ILSON, A.J.C.,
78,
90,
145,
254,
269
- W INEGARD, W.C.,
51,
54,
69
- W OOD,
274
- Wood's metal,
274
- WÖRWAG, G.,
142,
148
- W RIGHT, C.R.A.,
120
- W ULFF, J.,
194
- wüstite,
90
Z
- Zirconium, allotropy of,
113
- ZWINGMANN, G.,
191,
223